Wednesday, December 26, 2018

Extreme Fieldwork In The Karakoram Mountains

This remarkable passage from Colliding Continents by Mike Searle:

"After two weeks of acclimatizing on the Lobsang Spire and Cathedral granite cliffs above camp and establishing our attack camp full of supplies we were ready to go for the summit. I was keen to climb a line up through the granite cliffs in order to map out and sample a vertical profile through the granite batholith. These Karakoram granite spires provide a unique opportunity to map and sample over 3 kilometers deep into such a batholith. We left once again at 3 a.m. for the dangerous plod through the icefall, and arrived at the ice-shelf camp at about 10 a.m. As soon as the sun came on to the glacier, freezing night-time temperatures soared up to incredibly high hot temperatures above 350C. Frozen icicles dripping off the rock face turned into trickles of water and then into torrents. Huge avalanches of powder snow exploded down the steep granite faces all around us. This was nature in the raw: powerful, frightening, but at the same time immensely beautiful.

Next morning we left at the usual 3 a.m., roped up, and started climbing the steep ice face on the south face of Biale. Very soon the ice petered out and we were on vertical solid granite. Climbing vertical granite walls with a 20 kg rucksack, a rack full of slings and nuts and big plastic double boots was not easy. I was trying to record geological observations in the granites and put those onto a map at the same time; the sample collection was to be done on the way down. After two days of this steep and scary climbing we finally broke out of the cliffs onto a  large snowfield that led up to a knife-edge ridge. As we approached the ridge the most spectacular mountain panorama I have ever seen unfolded in front of us. We were in the middle of the Karakoram, with huge glaciers flowing all around us, separating ridiculously steep cliffs of pure granite".

The Himalaya ranges are the northern edge of the Indian continental crust which was deformed during the India-Asia collision. Similarly, the Karakoram ranges are the southern margin of the Asian continent which was deformed during the India-Asia collision. Mike Searle and his colleagues were trying to work out their deformation, metamorphic and uplift history.

In the satellite imagery below, I have overlain the major lithologic and structural elements of the India-Asia collision zone. The imagery covers the central and eastern Karakoram ranges.


The southern margin of the Asian plate is made up of two amalgamated terrains. In the mid Cretaceous (~110 million years ago) a separate terrain/microplate known as the Kohistan-Ladakh block existed south of the Asian continental mainland. As the Indian plate pushed northwards, oceanic crust which made up its leading edge dove under the Kohistan-Ladakh terrain. As the dense crust subducted, it heated up, releasing water trapped in the sediment cover. This water migrated upwards, lowering the melting point of rocks in the lower part of the Asian plate (mantle) and triggering melting. Magmatism and volcanism formed an intra-oceanic island arc system above the subduction zone. The Dras Arc Volcanics are part of this island arc, which continues westwards into Kohistan. The Ladakh batholith represents the root of this arc system, made up of granitic and granodioritic magma congealed in the deep subsurface. Volcanic rocks at the famous Khardung-La Pass are the surficial expression of the Ladakh magmatic system.

Between 70-80 million years ago, the Kohistan-Ladakh arc collided with the Asian mainland forming a composite terrain. The Main Karakoram Thrust-Shyok Suture marks the zone of collision between these two terrains. The Indian plate continued subducting under the Asian plate. Magmatic growth of the Kohistan-Ladakh batholith continued until about 50 million years ago. By this time, the Indian oceanic crust had been consumed and as a result the Indian continental crust collided with Asia. This collision zone is marked by the Indus-Tsangpo Suture.

The pre-collision tectonic setting of the Kohistan-Ladakh arc is depicted in the graphic posted below.


Source: Searle et. al. 1999

There is another model which proposes that the Kohistan-Ladakh arc first collided with the Indian plate around 85 million years ago. Collision of this combined plate with Asia then took place around 50 million years ago. I am ignoring this debate in this post.

Continental collision lead to crustal thickening on both sides of the suture zone. In the Karakoram region, high temperatures and pressures in the lower parts of the thickened crust resulted in metamorphism of buried rocks (Karakoram Metamorphic Complex). Eventually, temperatures in the buried crust exceeded the melting point of rocks, triggering magma generation. These post-collisional crustal melts intruded the surrounding metamorphic rocks forming sills (intrusions parallel to the layering) and dikes (intrusions cutting across the layering). Granites formed in this manner are most conspicuously exposed in the region around the Baltoro Glacier. These granites form many of the jagged spires and pinnacles that Mike Searle describes so vividly in his book. They are part of the Karakoram batholith.

Crustal melting and granite magma formation occurred in the thickened Indian plate as well, south of the Indus-Tsangpo suture zone. These granites are exposed along the crest of the High Himalaya ranges. The Himalayan post-collisional granites are beautiful to look at.  Faceted crystals of black tourmaline and red garnet, along with gleaming flakes of white mica, are set in a white to pink colored matrix made up of quartz and feldspar. The picture to the left shows a tourmaline bearing leucogranite from the Greater Himalaya Sequence making up the Panchachuli range in Kumaon, Uttarakhand. I collected it from the moraines of the Panchachuli glacier.

The Karakoram Batholith is a composite body made up of magmas formed during different times. Older granitic rocks (150-70 million years ago) in this batholith formed in an Andean type margin setting wherein the Tethyan ocean crust was subducting under the Asian continental plate.

Certain metamorphic minerals like kyanite, sillimanite and garnet are thermobarometers. Their elemental ratios tell us about the temperature and pressure prevalent during mineral growth. Geologists estimate that the sillimanite and kyanite bearing Karakoram metamorphic rocks were formed at 35 km depth. These metamorphic rocks, along with the earlier formed granites of the Karakoram batholith, eventually partially melted to form the Baltoro granites.

Geologists have also been able to work out when metamorphism and melting took place. Using radiogenic uranium isotopes trapped in zircon crystals they find that peak metamorphism took place in several pulses. The oldest metamorphic event occurred around as early as 60-65 million years ago, with the heat source likely being the collison of the Kohistan Arc. Subsequent metamorphic pulses, driven by crustal thickening,  have been dated to about 45 million yeas ago and an even younger event to about 16 million years ago.

Magmas which form the Baltoro granites intruded and crystallized between 20 million to 13 years ago, similar in age to the post collisional leucogranites of the High Himalaya which are 24 million to 15 million years old . Crustal melting and granite formation in the Karakoram continued sporadically until around 9 million years ago.

The deep crustal processes occurring in the Karakoram region were also taking place eastwards in the thickened crust below Tibet. In the Karakoram, metamorphic rocks and granites formed in the lower levels of the crust now lie spectacularly exposed along the steep mountain sides. Erosion over the past 30 million years has removed over 35 km of overburden, exhuming these deep crustal layers. The Tibetan plateau however is made up of sedimentary and volcanic rocks. Only the uppermost parts of the crust are exposed here. Karakoram equivalent high grade metamorphic rocks and crustal melt granites, which undoubtedly exist in this region, still lie deeply buried in the subsurface.

Why is there such a difference between Karakoram and the Tibetan Plateau in the level of crustal exposure?  Take a look at the satellite imagery. Karakoram is covered by snow, while much of the Tibetan Plateau lies bare. Karakoram receives rain and snowfall from both the India summer monsoon as well as the north westerlies bringing winter moisture from the Mediterranean and Caspian areas. Tibet lies in the rain shadow of both these systems.  High rates of stream incision and the enormous erosive power of glaciers has resulted in high rates of exhumation in the Karakoram, eventually exposing deeply buried crust. Low erosion rates in the arid Tibetan region has failed to cut deeply into the crust, resulting in exposure of only the uppermost levels of the crust. Both Karakoram and Tibet have an average elevation of about 5000 meters. In the Karakoram though there is prolific relief, with peaks in the 7000-8000 m range and valleys at 2000-3000 m elevation. Relief in Tibet is subdued.

Climate plays an enormous role in shaping the topography and evolution of mountains.

Tuesday, December 18, 2018

Interviews: Meteorite Researcher And A Palaeontologist

Came across these two interesting interviews with a meteorite researcher and a paleontologist.

Meenakshi Wadhwa grew up in Chandigarh, North India. She wanted to study architecture. She ended up being a meteorite researcher. Quanta Magazine highlights her path from college to Director of the Center for Meteorite Studies at Arizona State University.

I totally related to this!

Applying from India, at a time when there was no internet, I had the Barron’s guide to graduate schools in the U.S., which was outdated by like 10 years at that point. I didn’t care about geography or any of that. I didn’t care if it was East Coast or West Coast or the Midwest. It was all half a world away.

.. and this was pretty amazing-

We get something like 100 tons of stuff falling on the Earth every single day. Spread over the entire planet, it’s not all that much if you think about it. Most of that is sand-size particles — tiny, tiny particles. Things that are about the size of a car, or van-size bolides, they hit a few times a year. Something the size of the Chelyabinsk meteor [which exploded over Russia in 2013], that’s a few times a year.

It's a terrific interview.

Dr. Lisa White is a paleontologist. Her specialty is Diatoms. These are single celled algae. They have a lot to tell us about past ecology and climate.  African Americans are poorly represented in the geosciences, and Dr. White as the director of education and outreach at the University of California Museum of Paleontology is actively working to increase diversity in the geosciences.

An excerpt:

I work nationally on a number of boards and with working groups and communities that are constantly examining the diversity in geosciences. We know our numbers don’t compare to engineering and the biological sciences. African American students are more likely to know about those fields and see the direct link to jobs. So we do have a bit of an image problem.

[It can be] difficult for students to have access to information about geosciences careers. There aren’t often a lot of standalone courses in high school. But there are a lot of interdisciplinary connections between all the fields, especially geoscience engineering, chemistry, water science, even agriculture…soil science.

Black Enterprise has the full interview.

Its always fun to read about how people arrive at a particular career trajectory.  A casual conversation, a book read during a holiday, or a trip taken with friends or for some other work can lead someone down  a career path they never thought they would take.

Thursday, December 13, 2018

Books: Colliding Continents And Reading The Rocks

These two beauties came by mail!

Readers know that I have been traveling and writing about the Himalaya the past few years. I had gone to Delhi in 2010 to attend a wedding and casually asked my cousin whether he could recommend a trip to the Himalaya. After the wedding I ended up in Mukteshwar, Uttarakhand for a short stay. I was hooked and have been going regularly since. I realized that I knew almost nothing about Himalaya geology. My Masters course in Pune had barely touched the surface. There were no Himalaya geology experts among the faculty and that showed in the minimal attention it was given in the syllabus. After all these years,  I decided to use my trekking trips to observe the local geology and teach myself about the geological architecture of the Himalaya.  I have been reading from the research literature too. After 6 years of trekking, field observations and reading I can say that I do have a broad understanding of the lithology and structure of the Uttarakhand Himalaya. Mike Searle's book, based on his 30 years of field and lab work in the High Himalaya and Tibet, covering almost the entire mountain chain from the western extremity in Pakistan to Bhutan and the Indo-Myanmar ranges in the east, is going to add enormously to my understanding of the details of the geological processes in operation at the zone of collision between India and Asia and how they formed this enormous mountain belt.

Marcia Bjornerud's book comes highly recommended from my Twitter friends and colleagues. It tells the story of the earth by delving in to and elucidating the basic geological processes in operation on the surface and in the interior of the planet. I have been actively pursuing geology outreach for over a decade now, through my blog mainly, but more recently by taking people out in the field and conversing with them about the rocks we see around us and their place in the geologic history of the earth. I have been trying hard to improve my ability to explain basic concepts in an easy to understand language. I have a feeling this fine book will help me refine that skill.

I will be posting my thoughts and some excerpts from these two books from time to time.

Sunday, November 25, 2018

India Shale Gas: Environmental Concerns

Shale gas is natural gas trapped in very fined grained sedimentary rocks like shales. These rocks are not very permeable. To release the gas trapped in the tiny pore spaces, the rock is fractured by injecting water, sand and various chemicals into it at very high pressure. Several million gallons of fresh water is needed for such ' fracking' activity at any one site. 

Shashikant Yadav, Gopal K Sarangi and M P Ram Mohan in an essay in the Economic and Political Weekly explain the environmental concerns that shale gas production poses in India.

Regarding the guidelines for environmental management released by the government -

Further, the guidelines mention that water management is one of the key concerns. They state that the major and prime difference being in the hydraulic fracturing technologies requiring a large volume of water; the activities are likely to deplete water sources and cause pollution due to the disposal of produced water. However, instead of dealing with the water-specific issues, the guidelines (apart from explaining existing provisions) stated that the generic environment clearance process adopted by the Ministry of Environment, Forest and Climate Change (MoEFCC) will suffice to ascertain water-related issues posed by fracking. But, MoEFCC has not laid down any specific guidelines, policies, or manuals differentiating between conventional and unconventional gases to grant environment clearance.  More recently, despite the gaps, on 1 August, 2018, the cabinet approved a policy allowing companies to exploit shale gas in contract areas that were primarily allocated to exploit conventional gas.

..and this in the context of the ambiguous legal framework surrounding groundwater -

Considering the limited water legislation in India, the implementation of fracking may result in geopolitical and legislative complexities. For instance, shale rocks are usually adjacent to rocks containing useable/drinking water known as “aquifers.” While implementing the hydraulic fracking, the shale fluid can easily penetrate to aquifers leading to groundwater contamination. This contamination may result in methane-poisoning of water used for drinking and irrigational purposes. To avoid such contamination, as per industry standards, a project proponent must maintain a distance of 600 metres between aquifers and fracture zones (Davies et al 2012).

The Indian water legal regime is far away to make such specific observations, as aquifers are not defined in any of the Indian environmental regulatory or legal regime leading to a free pass for unregulated mixing of shale fluid and aquifers. Moreover, the landless have no right to groundwater, and accordingly peasants and tribal communities who have no ownership rights over land have no right on groundwater. Also, a project proponent may easily exploit groundwater while implementing the hydraulic fracking process with none or limited accountability of their actions.  In such a situation, the intent of “Public Trust Doctrine” is defeated, and the precautionary principle will be non-implementable.


Open Access.

Sunday, November 11, 2018

Stalactites And Other Calc Tufa Deposits Along Bageshwar Shama Road, Kumaon Himalaya

Traveling from Bageshwar to Shama, in Kumaon Uttarakhand, I came across a wondrous calc tufa deposit about a kilometer south of Kapkot village.

 The map below shows Bageshwar and Kapkot along Route 37. (Permanent Link).



Calc Tufa are calcium carbonate deposits which form on land in a subaerial environment. They are made up of the minerals calcite and, less commonly, aragonite. The most familiar of calcium carbonate deposits are sea floor and beach accumulations of shells and skeletons of marine organisms. Upon burial and hardening they turn into limestones. In the Proterozoic, before animals evolved the ability to biomineralize, vast thicknesses of limestones formed in the oceans by inorganic and bacterially mediated precipitation of calcium carbonate. Limestones that form in saline as well as fresh water lakes are also known.

Calc Tufa forms in the vicinity of springs, waterfalls, along river banks, caves and along hill slopes. They have a chalky texture, porous fabric and organic looking shapes. This is a result of calcium carbonate encrusting microbial, algal and moss colonies that inhabit these settings. Associated with these porous friable looking forms are more denser crystalline deposits. These are stalactites and various types of laminated and globular crusts. They are collectively called speleothems. They form generally in a cave setting by abiogenic precipitation from thin films of supersaturated water. This particular deposit containing both tufa and speleothems was along a steep hill slope with large cavities. The substrate rocks are the Mesoproterozoic age Deoban limestone and dolostones (made up of mineral dolomite). They are estimated to be around 1.5- 1.6 billion years old.

All along the exposure the rocks were shattered by prominent fracture zones. Rain water is weakly acidic. As it falls and moves through the cracks and fractures in these rocks it dissolves the minerals calcite and dolomite, becoming enriched in dissolved carbon dioxide (CO2) and calcium.  The partial pressure of CO2 (a measure of dissolved CO2 concentration) in this groundwater is more than the partial pressure of CO2 in the atmosphere. When groundwater enters a cave or emerges on a hill slope as a spring discharge, the lower partial pressure of CO2 in this open setting causes a degassing of CO2 from the groundwater. This results in the pH of the water to increase slightly, which in turn causes supersaturation of calcium carbonate in solution. Precipitation of calcium carbonate then begins on the cave walls and roof and on the hill slopes. It is possible that removal of CO2 by microbial photosynthesis may also be playing a role in triggering precipitation.

These tufa deposits occur at many places along the Bageshwar to Shama road. We finally stopped for a closer look at a largish looking deposit about a kilometer south of Kapkot. This was strictly road side geology on my part. We spent about half an hour at the deposit and so I am not presenting any detailed analysis or insights regarding this feature.

This is a complex deposit made up of varied types of tufa. We managed to photograph some beautiful calc tufa morphologies which I am posting below. My thanks to Pushkaraj Apte ( @pushkarajapte ) for contributing many of the photographs.

Lets get an idea of the size of the deposit. That's me, standing in front of the large cavern. You can see stalactites in the background.


 A peek inside the large cavity. It is about 3 meters in height and about 4 meters in width. I could have easily stood inside it. However, I did not enter it, fearing I would break some delicate mineral deposits which have formed on the floor of the cave.


Speleothems

Stalactites 1: The most striking of the formations are these stalactites. They range from thick columnar forms (1) which are more than a meter in length to smaller centimeter long thin delicate drips (2). The cave is damp. There is a thin film of water covering these columns suggesting ongoing mineral precipitation and growth of the stalactites. The floor of the cavern was also encrusted with deposits and partially covered with tufa debris.


 Stalactites 2: Along the hill slopes, exposed Deoban carbonate strata form ledges. Stalactites are growing on the undersides of these ledges. The bigger ones are about 1-2 feet in length.



 Botryoids:  At places botryoidal clusters (cave grapes) are seen. These hang from the roof (1) and accrete away from walls (2). They form by either radial or concentric growth of calcite (or aragonite) from a nucleation site. Each botryoid is about a centimeter or so in diameter.


Thin Platy Crusts: These thin (cm scale)delicate layers likely form in shallow films or pools of stagnant water on the floor of the cavity.


Flowstones?: These banded crusts  have formed on a slope from flowing water and likely represent abiogenic precipitation of calcite (flowstones). Alternatively they could be stromatolitic crusts formed by precipitation of calcite atop microbial sheaths and mats.


Calc Tufa:

Phytohermal Tufa: These are calcified moss deposits (a foot or so in height) which are formed on the floor of the cavity. They preserve the bushy morphology of the moss colonies. Calcite encrusted and eventually entirely replaced the moss colonies, turning them into fossilized organic structures.


Microhermal Tufa or Phytohermal Tufa: The thin tube like structures (few cm in length) of this calc tufa deposit suggests that it formed by mineral encrustation of filamentous algae or bacterial colonies. However, I cannot be sure. This too could be a moss colony.


Spongiform Tufa: Massive looking with dispersed holes. Such structures from by mineral encrusting organic matter (moss, microbial mats) draping the hillsides. The open spaces between the organic matter and decay of vegetation gives the deposit a sponge like texture. Some larger cavities (about 6 inches across) are lined with layered mineral deposits.


I found this broken piece along the road side next to the deposit. It is made up of small globular aggregates and columns which have accreted upon a substrate of spongiform tufa.


In this transverse section you can see clearly the calcium carbonate layers that have built up the column.


A cross section of the larger stalactites will also reveal its layered nature. Stalactites with such growth layers are of importance in reconstructing past climates. The oxygen in the calcite (CaCO3) provides the clue. Variations in the ratio of the two isotopes of oxygen (O18/O16) which are bound up in calcite are indicators of differences in the strength of rainfall. The lighter isotope (O16) is preferentially retained in the vapor phase. During phases of weak monsoons or drought, rain becomes enriched in the heavier isotope (O18). Calcite layers precipitated from this water will be enriched in the heavier isotope. In contrast, during strong monsoon phases, rain and groundwater becomes relatively enriched in the lighter isotope. As a result, calcite layers will inherit a 'lighter' oxygen isotope signal.

For the Indian subcontinent, reconstruction of the past variability of Asian monsoons going back hundreds to thousands of years, are based on precious few data points, spread rather sparsely across India. Recently, Gayatri Kathayat and colleagues published a study of Indian monsoon history over the past 5700 years based on the oxygen isotope record of cave stalactites from Sahiya in Uttarkhand, located about 200 km WNW of where we were. Judging by the size of some of the stalactites, I am guessing that deposition at this Kapkot site has been going on for a few hundred years at least. I wonder if this deposit can be a new paleo climate data source.

I did have another intriguing thought. Is the profusion of calc tufa deposits along road cuts in this region just a coincidence? Is it possible that blasting and cutting the hill side for building the road enhanced fractures and triggered collapse of blocks, resulting in the formation of caverns, and creating conditions favorable for calc tufa precipitation?   If so, then this deposit may be at most a hundred years old. Wild!